![]() ![]() ![]() Of aluminums on both sides, and the same thing is And so aluminum just can'tĪppear out of thin air by virtue of some magical reaction. The right-hand side? Well on the right-hand Here on the left-hand side, how many aluminums do we have? Well on the left-hand You might notice that you don't have the same number "What do I have to balance?" Well if you look carefully, And so you might say, "Okay, well what's "the balancing business all about? "I have a chemical reaction. And the aluminum oxide molecule has two aluminum atoms and three oxygen atoms. The appropriate conditions they will react to form aluminum oxide. So if I take an atom ofĪluminum and I add it to a dioxygen molecule, so a molecule that has two oxygens with it, under Is a chemical equation? Well this is a chemicalĮquation right over here. If we work through this carefully and methodically,Īnd we also appreciate the art of balancing chemical equations, that it's actually not too bad. In this situation, since we assume copper does not react, the reactants are only H +(aq) and Fe(s).Equations is one of those concepts in chemistry that ![]() Step 1: Write a balanced equation after determining the products and reactants. % error = | theoretical - experimental | / theoretical * 100% Check your result by calculating the molar mass of the molecular formula and comparing it to the experimentally determined mass.Įxperimentally determined mass = 120.056 g/mol Multiply the ratio from step 4 by the subscripts of the empirical formula to get the molecular formula.Ħ. ![]() If the answer is not close to a whole number, there was either an error in the calculation of the empirical formula or a large error in the determination of the molecular mass.ĥ. Since 3.9984 is very close to four, it is possible to safely round up and assume that there was a slight error in the experimentally determined molecular mass. Divide the experimentally determined molecular mass by the mass of the empirical formula. Determine the molecular mass experimentally. In the example above, it was determined that the unknown molecule had an empirical formula of CH 2O.ġ. (1/0.0332)(0.0333mol C : 0.0665mol H : 0.0332 mol O) => 1mol C: 2 mol H: 1 mol Oįrom this ratio, the empirical formula is calculated to be CH 2O. (0.0666mol O + 0.0332 mol O) - 0.0666mol O = 0.0332 mol OĬonstruct a mole ratio for C, H, and O in the unknown and divide by the smallest number. With this we can use the difference of the final mass of products and initial mass of the unknown organic molecule to determine the mass of the O 2 reactant.Ġ.333mol CO 2(44.0098g CO 2/ 1mol CO 2) = 1.466g CO 2ġ.466g CO 2 + 0.599g H 2O - 1.000g unknown organic = 1.065g O 2ġ.065g O 2( 1mol O 2/ 31.9988g O 2)( 2mol O/ 1mol O 2) = 0.0666mol O Using the Law of Conservation, we know that the mass before a reaction must equal the mass after a reaction. This will give you the number of moles from both the unknown organic molecule and the O 2 so you must subtract the moles of oxygen transferred from the O 2.Ġ.0333mol CO 2 ( 2mol O/ 1mol CO 2) = 0.0666 mol OĠ.599g H 2O ( 1mol H 2O/18.01528 g H 2O)( 1mol O/ 1mol H 2O) = 0.0332 mol O Since all the moles of C and H in CO 2 and H 2O, respectively have to have came from the 1 gram sample of unknown, start by calculating how many moles of each element were present in the unknown sample.Ġ.0333mol CO 2 ( 1mol C/ 1mol CO 2) = 0.0333mol C in unknownĠ.599g H 2O ( 1mol H 2O/ 18.01528g H 2O)( 2mol H/ 1mol H 2O) = 0.0665 mol H in unknownĬalculate the final moles of oxygen by taking the sum of the moles of oxygen in CO 2 and H 2O. ![]()
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![]() ![]() ![]() There are huge stars like Prince, Joni Mitchell, and Neil Young, and behind-the-scenes masters like Memphis soul great Teenie Hodges and smooth-rock assassin Larry Carlton. There are peerless virtuosos like Pat Metheny, Yvette Young, and Steve Vai, as well as primitivists like Johnny Ramone and Poison Ivy of the Cramps. The list has rock, jazz, reggae, country, folk, blues, punk, metal, disco, funk, bossa nova, bachata, Congolese rumba, flamenco, and much more. The earliest entrant on the list (folk music icon Elizabeth Cotten) was born in 1893, the youngest (indie-rock prodigy Lindsey Jordan) was born in 1999. ![]() We wanted to show the scope of the guitar’s evolution. But mythic guitar gods like Jimmy Page, Brian May, and Eddie Van Halen are only one part of the story. Guitar players are often as iconic as the lead singers for the bands they play in. Our new expanded list was made by the editors and writers of Rolling Stone. It was compiled by a panel of musicians, mostly older classic rockers. Rolling Stone published its original list of the 100 Greatest Guitarists in 2011. That’s why thinking about what makes a great guitarist is so much fun. Anybody can pick up a little guitar in no time at all, but you can spend a lifetime exploring its possibilities. It is who I am.” The guitar is the most universal instrument, the most primal, and the most expressive. “My guitar is not a thing,” Joan Jett once said. ![]() ![]() ![]() ![]() In 2020, results of a genetic analysis of red panda samples showed that the red panda populations in the Himalayas and China were separated about 250,000 years ago. The Chinese subspecies has a more curved forehead and sloping snout, a darker coat with a less white face and more contrast between the tail rings. The Himalayan subspecies has a straighter profile, a lighter coloured forehead and ochre-tipped hairs on the lower back and rump. It is traditionally divided into two subspecies: the Himalayan red panda ( A. The modern red panda is the only recognised species in the genus Ailurus. In 1902, Oldfield Thomas described a skull of a male red panda specimen under the name Ailurus fulgens styani in honour of Frederick William Styan who had collected this specimen in Sichuan. The red panda was described earlier by Thomas Hardwicke in 1821, but his paper was only published in 1827. Cuvier's description was based on zoological specimens, including skin, paws, jawbones and teeth "from the mountains north of India", as well as an account by Alfred Duvaucel. The red panda was described and named in 1825 by Frederic Cuvier, who gave it its current scientific name Ailurus fulgens. Taxonomy Watercolour painting of a red panda commissioned by Thomas Hardwicke c. The specific epithet fulgens is Latin for 'shining, bright'. The genus name Ailurus is adopted from the Ancient Greek word αἴλουρος ailouros meaning 'cat'. The Nepali words "nigalya ponya" has been translated as "bamboo footed" and is thought to be the red panda's Nepali name in English, it was simply called panda, and was the only animal known under this name for more than 40 years it became known as the red panda or lesser panda to distinguish it from the giant panda, which was formally described and named in 1869. The word पञ्जा pajā or पौँजा pañjā means "ball of the foot" and "claws". The origin of the name panda is uncertain, but one of the most likely theories is that it derived from the Nepali word "ponya". It is featured in animated movies, video games, comic books and as the namesake of companies and music bands. ![]() Regional captive breeding programmes for the red panda have been established in zoos around the world. It is protected in all range countries.Ĭommunity-based conservation programmes have been initiated in Nepal, Bhutan and northeastern India in China, it benefits from nature conservation projects. The species has been listed as Endangered on the IUCN Red List since 2015. It is threatened by poaching as well as destruction and fragmentation of habitat due to deforestation. Red pandas mate in early spring, with the females giving birth to litters of up to four cubs in summer. It feeds mainly on bamboo shoots and leaves, but also on fruits and blossoms. The red panda inhabits coniferous forests as well as temperate broadleaf and mixed forests, favouring steep slopes with dense bamboo cover close to water sources. The evolutionary lineage of the red panda ( Ailuridae) stretches back around 25 to 18 million years ago, as indicated by extinct fossil relatives found in Eurasia and North America. It is not closely related to the giant panda, which is a bear, though both possess elongated wrist bones or " false thumbs" used for grasping bamboo. The red panda's place on the evolutionary tree has been debated, but modern genetic evidence places it in close affinity with raccoons, weasels, and skunks. The two currently recognised subspecies, the Himalayan and the Chinese red panda, genetically diverged about 250,000 years ago. The red panda was formally described in 1825. ![]() It is well adapted to climbing due to its flexible joints and curved semi-retractile claws. It has dense reddish-brown fur with a black belly and legs, white-lined ears, a mostly white muzzle and a ringed tail. The red panda ( Ailurus fulgens), also known as the lesser panda, is a small mammal native to the eastern Himalayas and southwestern China. ![]() ![]() A signed delivery receipt without notations of missing, damaged, or incorrect item(s) represents your acceptance of the complete order in perfect condition. This map will be a recreation of the Pizzaria from the game Five Nights At Freddys. This is just a custom FNAF 1 map with a different layout and bits of the movie too. In the event that there are visible signs of damage or missing or incorrect pieces, please indicate the problem on the Delivery Note and contact us within 48 hours of delivery. Ladies and gentlemen, boys and girls welcome to Freddy Fazbears Pizza, where fantasy and fun come to life. Please examine every order upon delivery.
![]() Any themes you downloaded afterwards are saved in your own user profile in the following location. Note that this folder only stores all default themes that come with Windows 10 installation. But that doesn’t seem to be the case, at least for now, if you look at what’s in that folder. Judging by the name of it, it should be the home for all spectacular images at 4K resolution. ![]() Now what is this 4K folder for? I’ve got no idea. And they are stored in Wallpaper folder like below.Īnd listed in Personalization control panel applet as following: If you haven’t installed any themes, these are 3 themes by default that come with Windows 10. The Wallpaper folder is where all theme’s wallpapers are saved. But you can use the Browse button to pick a picture from your own list. Note that adding more pictures into the folder won’t easily get you to set a different Lock Screen background in Settings, since it only lists the first 5 pictures in Personalization. Here is what you will find out if you go into it. The Screen folder is where all Lock Screen backgrounds are stored. Open File Explorer (press Win+E), navigate to this folder, and you will see 3 folders there, 4K, Screen, and Wallpaper. ![]() Like these beautiful wallpapers and lock screen backgrounds on newly installed Windows 10 computer? Wondering where they are stored on your computer so you can retrieve them for your own use? Let’s find out.Įverything is stored in a single location, the web folder in default Windows installation folder, such as: c:\windows\web ![]() ![]() ![]() The lettering style is the heart and soul of graffiti art. Let's explore some of the key elements: Lettering Styles Understanding these elements is crucial for creating authentic and captivating graffiti artwork. Graffiti art incorporates various elements that contribute to its distinct style and visual impact. Since then, it has evolved into a global phenomenon, blending street culture with artistic creativity. In modern times, graffiti emerged as a form of artistic rebellion and cultural commentary on the streets of New York City in the 1970s. ![]() ![]() From ancient cave paintings to political slogans, humans have used public spaces to express their thoughts and emotions. Graffiti art has a rich and diverse history that dates back thousands of years. We will explore the history of graffiti art, examine its Core elements, and recognize the significance of wild style graffiti. Understanding the Basics of Graffiti Artīefore delving into wild style lettering, it's essential to have a solid understanding of the fundamentals of graffiti art. Whether you're a beginner or an experienced graffiti artist, this guide will provide you with valuable insights and techniques to take your artistry to the next level. In this article, we will dive deep into the world of wild style graffiti art and learn how to Create captivating lettering that reflects your individual style. Among the various styles of graffiti, wild style stands out with its intricate designs and flamboyant lettering. Graffiti art has emerged as a powerful form of self-expression and creative outlet.
![]() ![]() The Bola roots humans in place for 25 seconds and wild dinos for 30 seconds. It can be thrown and when it hits a target, it wraps around their feet or body and entangles them. Credit for both methods goes to YouTuber Teachers Game Too, so be sure to check out their full video detailing these methods in the video below.The Bola is a primitive weapon used to immobilize small or medium sized creatures. So there you have it, two solid methods that you can start using immediately to ensure that you get high-level dinos spawning on the island of ARK Survival Ascended. The mod itself has a few options you can use, such as setting the wild dinos to the previous DLC Ragnarok levels, Equalized levels (dinosaurs of all levels will spawn more equally, including higher level ones), or High Levels where the dinos will spawn with high levels in the same frequency as they used to with dinos at lower levels (it inverts the spawning and level calculations). Kitzykatty's mod will give us free control over the dino spawn levels in the game, which is far easier to manage than the holistic difficulty settings method. To install it, head over to the mod menu, search for the mod name listed above, and install it. More specifically, you can use the " Custom Dino Levels " mod created by kitzykatty, which has this feature built-in. Now, if you don't fancy the idea of changing your in-game difficulty, you can use mods to change the level of your spawned-in dinos. It should be noted that this does increase the difficulty of the game (naturally), but in most cases, the dinos do not deal that much extra damage, and by the time you find dinos that do, you'll already be strong enough to handle them. Next, you'll need to change the World's default difficulty which forces dinos of level 150 to spawn. While you can change some of the other settings as you like, these two are the only required ones needed to essentially force the game to spawn in higher-level dinos. Then in the "World" sub-tab, scroll down and turn on the "Maximum Difficulty" toggle. The first thing to do here is in the "Player" sub-tab, change the game difficulty at the bottom in the " Player " sub-tab by selecting "Choose Difficulty" and " Hard. To get higher-level dino spawns using the game settings (for Unofficial or Solo games), the first thing you'll need to do is head to the main menu, and when creating a new game or Story ARK, open up the "Game Rules" tab. Using In-Game Settings to Increase Dino Levels One of the settings you need to change to get high-level dinos is changing the player game difficulty. Thankfully, there are two ways to ensure that your island only spawns high-level dinos through the use of game settings or mods, so let's discuss both approaches below. How To Get High-Level Dinosaurs in ARK Survival AscendedĪs previously mentioned, when you load into ARK Survival Ascended, there will be tons of low-level dinos roaming around, and finding high-level ones is extremely tough, especially for new players. In this guide, we will provide precise instructions on how to obtain high-level dinos in ARK Survival Ascended. It can be quite a time-consuming task to wander around for extended periods, hoping to encounter a high-level dino, only to either be unsuccessful or lose it due to unfortunate circumstances.įortunately, there's a relatively straightforward way to acquire high-level dinosaurs in the game by adjusting just a couple of settings. Whether you're a newcomer or a seasoned player in ARK Survival Ascended, one early challenge you'll likely face is the difficulty of locating high-level dinosaurs in the game. ![]() ![]() Models designed to forecast events that can be classed this way should be able to distinguish the one from the other in some useful way. Exactly what constitutes “useful,” though, will depends on the nature of the forecasting problem. ![]() Discrimination refers to a model’s ability to distinguish accurately between cases in different categories: heads or tails, incumbent or challenger, coup or no coup. So, what kinds of errors should we look for? Statistical forecasters draw a helpful distinction between discrimination and calibration. But we can still assess whether the errors in the model estimates were small enough to warrant confidence in that model, and make its application useful and worthwhile. It’s not realistic to expect any model to get exactly the right answer-the world is just too noisy, and the data are too sparse and (sadly) too low quality. The world is inherently uncertain, and sound forecasts will reflect that uncertainty instead of pretending to eliminate it. The important point here is that these forecasts are probabilities, not absolutes, and we really ought to evaluate them as such. So when is a forecast like Silver’s or Linzer’s wrong? If a meteorologist says there’s a 20 percent chance of rain, and it rains, was he or she wrong? If an analyst tells you there probably won’t be a revolution in Tunisia this year and then there is one, was that a “miss”? Over at Votamatic, Drew Linzer’s model gives Obama a stronger chance of re-election-better than 95 percent-but even that estimate doesn’t entirely eliminate the possibility of a Romney win. As of today, his model of the presidential contest pegs Obama’s chances of re-election at about 70 percent-not exactly a toss-up, but hardly a done deal, either. Silver won’t try to call the race one way or the other instead, he’ll estimate the probabilities of all possible outcomes. Or, if I say Obama will win in November but Romney does, I was obviously wrong.īut here’s the thing: few forecasters worth their salt will make that kind of unambiguous prediction. ![]() For example, if I predict that a flipped coin is going to come up heads but it lands on tails, my forecast was incorrect. ![]() What caught my mind’s eye in Hounshell’s tweet, though, was what it suggested about how we conventionally assess a forecast’s accuracy. The question at the head of this post seems easy enough to answer: a forecast is wrong when it says one thing is going to happen and then something else does. Silver uses a set of statistical models to produce daily forecasts of the outcome of the upcoming presidential and Congressional elections, and I suspect that Hounshell was primarily interested in how the accuracy of those forecasts might solidify or diminish Silver’s deservedly stellar reputation. Silver writes the widely read FiveThirtyEight blog for the New York Times and is the closest thing to a celebrity that statistical forecasting of politics has ever produced. This topic came up a few days ago when Foreign Policy managing editor Blake Hounshell tweeted: “Fill in the blank: If Nate Silver calls this election wrong, _.” ![]() ![]() ![]() por el momento la solución temporal que encontré fue exportar de revit a 3dmax y de 3dmax a lumion. les volví a a enviar un correo mostrando todas las quejas que hay al respecto a ver si nos solucionan el problema. yo les escribí directamente al correo de lumion y me respondieron que actualizara revit, pero ese no es el problema, el problema es este plugin que lo dañaron actualizando. He estado mirando y hay muchas personas con el mismo problema, esta ocurriendo desde el 12 de junio, ellos hicieron una actualización el 11 de junio y al parecer dañaron el plugin. However, although the plugin is free, the main application can be obtained as a trial, a student version, or a commercial version. If you need any more assistance, please reach out to our support team here: ![]() Lumion (the main application) The role of the plugin is to seamlessly transfer the information from the CAD software to Lumion. the Lumion plugin (downloaded from here which ensures a connection) 3. If you need any more assistance, please reach out to our support team here: Hi, There are three components that are required to run the LiveSync connection: 1. However, although the plugin is free, the main application can be obtained as a trial, a student version, or a commercial version. The role of the plugin is to seamlessly transfer the information from the CAD software to Lumion. the Lumion plugin (downloaded from here which ensures a connection) There are three components that are required to run the LiveSync connection:Ģ. Automatic model importing into Lumion (no need to separately import a model) Real-time materials synchronization and visualization The ability to add and save Lumion’s beautiful materials to your LiveSync project Camera synchronization between Revit and Lumion Realtime model synchronization between Revit and Lumion Change the model’s shape in Revit to test a modified design, and you’ll instantly see the model updated in Lumion so you can view it with accurate lighting and shadow, surrounding contexts such as urban neighborhoods or rural settings, and beautiful, realistic materials. The free Lumion LiveSync plugin lets you set up a simultaneous, real-time connection between your 3D model in Revit and Lumion 10.3. ![]() IMPORTANT: Do you need help? Please contact us via our support page: Īlways get a real-time view of your Autodesk® Revit® 3D model in Lumion’s breathtaking, full context environments with LiveSync for Revit. ![]() ![]() ![]() The wooden gyms are tan and have four legs with four different color balls in the middle that are connected by two ropes on the sides. Babies lay under the gym to play with the hanging mobiles. Hazard: Babies can strangle on the side rope crossbars on the baby gyms.ĭescription: This recall involves PlanToys baby gyms that are set on the floor for babies. ![]() PlanToys Recalls Baby Gyms Due to Strangulation Hazard ET Monday through Friday or online at and click on Product Recalls for more information. Remedy: Consumers should immediately stop using the recalled craft kits and return them to Babies“R”Us or Toys“R”Us for a full refund or store credit.Ĭonsumer Contact: Toys“R”Us at 80 from 9 a.m. Importer(s): Toys“R”Us Inc., of Wayne, N.J.ĭistributor(s): Toys“R”Us Inc., of Wayne, N.J. Sold At: Babies“R”Us and Toys“R”Us stores nationwide from January 2017 through October 2017 for about $10. The “totally me!” logo is printed on the front of the craft kit box. Model number AD11244 is printed on the bottom of the box. No injuries have been reported.ĭescription: This recall involves “totally me!” clay craft kits. Incidents/Injuries: The firm has received three reports of mold in the clay. Hazard: Mold can be present in the clay, posing a risk of respiratory or other infections in individuals with compromised immune systems, damaged lungs or an allergy to mold. It is illegal to resell or attempt to resell a recalled consumer product. Consumers should stop using this product unless otherwise instructed. Toys“R”Us Recalls Clay Craft Kits Due to Risk of Mold Exposure Sold at Babies“R”Us and Toys“R”Us Although toy recalls are rare, they are an important part of a robust safety system, creating a “safety net” that helps to remove faulty product from the distribution chain and, when necessary, out of consumers’ homes. Because the toy industry designs its products specifically for children, toys are held to a high standard of safety. ![]() |
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